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It was particularly significant in antiquity, giving its name to the Bronze Age. HistoryThe introduction of bronze was significant to any civilization that encountered it. Tools, weapons, armor, and various building materials like decorative tiles made of bronze were harder and more durable than their stone and copper ("Chalcolithic") predecessors. In early use, the natural impurity arsenic sometimes created a superior natural alloy; this is termed arsenical bronze (of which Ötzi the Iceman's axe is an example). The earliest tin-alloy bronzes date to the late 4th millennium BC in Susa (Iran) and some ancient sites in Luristan (Iran) and Mesopotamia (Iraq). While copper and tin can naturally co-occur, the two ores are rarely found together (although one ancient site in Thailand and one in Iran provide counterexamples). Serious bronze work has therefore always involved trade (and the compelling idea that there were really traders in such goods). In fact, archaeologists suspect that a serious disruption of the tin trade precipitated the transition to the Iron Age. In Europe, the major source for tin was Great Britain. Phoenician traders visited Great Britain to trade goods from the Mediterranean for tin. Bronze was stronger than the era's iron; quality steels were not widely available until thousands of years later, although they were produced in late Celtic oppida and in China. But the Bronze Age gave way to the Iron Age, perhaps because the shipping of tin around the Mediterranean (or from Great Britain) became more limited during the major population migrations around 1200 – 1100 BC, which dramatically limited supplies and raised prices . Bronze was still used during the Iron Age, but for many purposes the weaker iron was found to be sufficiently strong. As ironworking improved, iron became both cheaper and stronger, eclipsing bronze in Europe by the early to mid-Middle Ages.
PropertiesWith the exception of steel, bronze is superior to iron in nearly every application. Although bronze develops a patina, it does not oxidize beyond the surface. It is considerably less brittle than iron and has a lower casting temperature. Copper-based alloys have lower melting points than steel and are more readily produced from their constituent metals. They are generally about 10 percent heavier than steel, although alloys using aluminium or silicon may be slightly less dense. Bronzes are softer and weaker than steel, bronze springs are less stiff (and so store less energy) for the same bulk. It resists corrosion (especially seawater corrosion) and metal fatigue better than steel and also conducts heat and electricity better than most steels. The cost of copper-base alloys is generally higher than that of steels but lower than that of nickel-base alloys.
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